2inch SiC ingot Dia50.8mmx10mmt 4H-N monocrystal
Fasahar Ci gaban SiC Crystal
Halayen SiC suna sa ya yi wahala girma lu'ulu'u ɗaya.Wannan shi ne yafi saboda gaskiyar cewa babu wani lokaci na ruwa tare da rabon stoichiometric na Si: C = 1: 1 a matsa lamba na yanayi, kuma ba zai yiwu ba don girma SiC ta hanyar mafi girma girma hanyoyin, irin su hanyar zane kai tsaye kuma hanyar faɗowa crucible, waɗanda su ne ginshiƙan masana'antar semiconductor.A ka'ida, wani bayani tare da stoichiometric rabo na Si: C = 1: 1 za a iya samu ne kawai a lokacin da matsa lamba ne mafi girma fiye da 10E5atm da zafin jiki ne mafi girma fiye da 3200 ℃.A halin yanzu, hanyoyin da ake amfani da su sun haɗa da hanyar PVT, hanyar ruwa-lokaci, da kuma hanyar saka sinadarai masu zafi mai zafi.
SiC wafers da lu'ulu'u da muke samarwa galibi ana girma ta hanyar jigilar tururi ta jiki (PVT), kuma mai zuwa shine taƙaitaccen gabatarwa ga PVT:
Hanyar safarar tururi ta jiki (PVT) ta samo asali ne daga fasahar sublimation na gas-lokacin da Lely ya ƙirƙira a cikin 1955, wanda aka sanya SiC foda a cikin bututu mai graphite kuma mai zafi zuwa babban zafin jiki don sa foda na SiC ya lalace kuma ya lalace, sannan graphite. bututu an sanyaya ƙasa, kuma bazuwar gas-lokaci sassa na SiC foda ana ajiye da crystallized kamar SiC lu'ulu'u a cikin kewaye yankin na graphite tube.Kodayake wannan hanyar tana da wahala a sami manyan lu'ulu'u ɗaya na SiC masu girma da yawa kuma tsarin sakawa a cikin bututun graphite yana da wahalar sarrafawa, yana ba da ra'ayoyi ga masu bincike na gaba.
YM Tairov et al.a Rasha ya gabatar da manufar kristal iri a kan wannan tushen, wanda ya warware matsalar siffar crystal marar sarrafawa da matsayi na tsakiya na SiC crystals.Masu bincike na gaba sun ci gaba da ingantawa kuma a ƙarshe sun haɓaka hanyar canja wurin tururin jiki (PVT) wanda ake amfani da shi a masana'antu a yau.
A matsayin farkon hanyar ci gaban kristal SiC, PVT a halin yanzu shine mafi girman hanyar girma don lu'ulu'u na SiC.Idan aka kwatanta da sauran hanyoyin, wannan hanya tana da ƙananan buƙatu don kayan haɓaka haɓaka, tsarin haɓaka mai sauƙi, mai ƙarfi mai ƙarfi, cikakken ci gaba da bincike, kuma an riga an haɓaka masana'antu.
Cikakken zane
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